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The concepts of symmetry adapted rotational modes and strain modes are used to successfully understand the structural changes and the unusual thermal expansion behaviour of CAPyz. Chapter 4 demonstrates the use of systematic and exhaustive symmetry adapted distortion mode subgroup search methods to solve the high temperature structure of 5,6dichloro methylbenzimidazole (DC MBI) successfully from powder diffraction data. It describes how different models can be automatically tested against powder diffraction data and how the best structural description can be chosen.

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